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Carbon dioxide flux and isotopic composition from sedimentary rock weathering, Waiapu River catchment, New Zealand

Dataset title Carbon dioxide flux and isotopic composition from sedimentary rock weathering, Waiapu River catchment, New Zealand
Dataset creators Tobias Roylands, Durham University, UK
Robert G. Hilton, University of Oxford, UK
Mark H. Garnett, NEIF Radiocarbon Laboratory, UK
Guillaume Soulet, Ifremer, France
Dataset theme Geoscientific Information
Dataset abstract

These data were collected to study oxidative weathering processes in the Waiapu River catchment, New Zealand, with potential carbon release sourced from the oxidation of petrogenic organic carbon or carbonate dissolution coupled to the oxidation of sulfide minerals.

There, in mudstones exposed in a highly erosive gully complex, in situ CO2 emissions were measured with drilled gas accumulation chambers following the design by Soulet et al. (2018, Biogeosciences 15, 4087-4102, https://doi.org/10.5194/bg-15-4087-2018).

Temporal and spatial variability in CO2 flux can be put in context with environmental changes (e.g., temperature and hydrology).

For this, CO2 release from 5 different chambers, which were installed over a transect of ~ 10 m length in a gully above a nearby streambed, was measured several times over a short study period (circa one week).

In addition, the gaseous CO2 storage (partial pressure) in the shallow weathering zone was measured prior to a CO2 flux measurement.

To understand the source of CO2, gas samples were collected and their stable and radioactive carbon isotope compositions determined.

In this process, we identified a contaminant, which was associated with the chamber installation, that can be traced in the gas samples that were collected within 4 days following the installation.

Details of the subsequent data analysis and interpretation can be found in: Roylands et al. 2022, Chemical Geology: Capturing the short-term variability of carbon dioxide emissions from sedimentary rock weathering in a remote mountainous catchment, New Zealand.

This work was supported by the European Research Council (Starting Grant to Robert G. Hilton, ROC-CO2 project, grant 678779).

Dataset content dates 29/04/2018 - 05/05/2018
Dataset spatial coverage Gully complex in Waiapu River catchment, New Zealand 37.85986° S, 178.19028° E
Dataset supply format MS Excel
Dataset language English-United Kingdom
Dataset discovery metadata record Discovery Link to the dataset's BGS Discovery Metadata record
Dataset publisher NERC EDS National Geoscience Data Centre
Dataset publication date 1st July 2022
Dataset digital object identifier(DOI) 10.5285/467fcf54-eb20-4a19-a62d-8867516de87c
Dataset citation text Roylands, T., Hilton, R.G., Garnett, M.H., Soulet, G. (2022). Carbon dioxide flux and isotopic composition from sedimentary rock weathering, Waiapu River catchment, New Zealand. NERC EDS National Geoscience Data Centre. (Dataset). https://doi.org/10.5285/467fcf54-eb20-4a19-a62d-8867516de87c
Constraints and terms of use This data set is available under Open Government Licence, subject to the following acknowledgement accompanying any reproduced materials: "Contains data supplied by permission of the Natural Environment Research Council [YEAR]".
Access the dataset https://webapps.bgs.ac.uk/services/ngdc/accessions/index.html#item173494
Further Information

Published Paper:

Tobias Roylands, Robert G. Hilton, Mark H. Garnett, Guillaume Soulet, Josephine-Anne Newton, Joanne L. Peterkin, Peter Hancock. Capturing the short-term variability of carbon dioxide emissions from sedimentary rock weathering in a remote mountainous catchment, New Zealand.

https://doi.org/10.1016/j.chemgeo.2022.121024